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Barium phosphate

Barium phosphate
Names
IUPAC name
Barium phosphate
Identifiers
3D model (JSmol)
ChemSpider
ECHA InfoCard 100.033.491 Edit this at Wikidata
EC Number
  • 236-856-9
  • InChI=1S/3Ba.2H3O4P/c;;;2*1-5(2,3)4/h;;;2*(H3,1,2,3,4)/q3*+2;;/p-6
    Key: WAKZZMMCDILMEF-UHFFFAOYSA-H
  • [O-]P(=O)([O-])[O-].[O-]P(=O)([O-])[O-].[Ba+2].[Ba+2].[Ba+2]
Properties
Ba3(PO4)2
Molar mass 601.9 g/mol
Appearance Powder
Structure
Rhombohedral
Hazards
GHS labelling:[1]
GHS07: Exclamation mark
Warning
H302, H332
P261, P264, P270, P271, P301+P317, P304+P340, P317, P330, P501
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).

Barium phosphate (also known as barium orthophosphate) is an inorganic phosphate of barium with the molecular formula Ba3(PO4)2. It is usually found as a white, odorless powder which is insoluble in water.[1]

Preparation

The general chemical reaction for the synthesis of barium phosphate powder is:[2]

Ba(NO3)2 + 2NH4H2PO4 → Ba3(PO4)2 + 2NH4NO3 + 4HNO3

Structure

Its crystal structure is rhombohedral with a space group of R3m, the same as in strontium phosphate.[3]

Properties

Barium phosphate exhibits properties such as high refractive index, low melting point, low glass transition temperature, high transparency to ultraviolet light, and high thermal expansion coefficient.[4]

See also

References

  1. ^ "Barium Phosphate: Versatile Uses and Key Benefits". Eureka. Retrieved 11 March 2025.[unreliable source?]
  2. ^ "Ba3(PO4)2 Photocatalyst for Efficient Photocatalytic Application" (PDF). p. 9. Retrieved 23 April 2025.
  3. ^ Zachariasen, W. H. (2 November 1948). "The crystal structure of the normal orthophosphates of barium and strontium". Acta Crystallographica. 1 (5): 263–265. doi:10.1107/S0365110X48000697.
  4. ^ "Barium Phosphate Powder". Sigma Aldrich. Retrieved 12 March 2025.